北京师范大学化学学院/文理学院教授，先进材料研究中心副主任，校学位委员会委员。主要从事热电材料和非线性光学材料构效关系研究，将结构化学、理论化学和实验结合，辅助新型功能材料的发现、判明功能材料性能提升的可行方向、以及阐明功能材料的结构-性能关系。通过理论计算和结构设计、结合实验合成和探测，提出了阳离子化学裁剪、协同取代等结构调控新策略及性能提升新方案；发现系列高效、有实用价值的窄带半导体热电材料和宽带非线性光学材料。担任Journal of Solid State chemistry杂志编委，荣获北京市、中国科学院、京博科技奖优秀毕业生指导教师等。

教育背景

1989.09-1993.06 北京师范大学，化学，理学学士

1993.09-1996.06 北京师范大学，物理化学，理学硕士

1996.09-1999.06 福州大学，物理化学，理学博士

工作经历

1999.07-2001.07 中科院福建物构所，博士后

2001.08-2004.01 美国亚利桑那州立大学，博士后

2004.02-2004.12 中科院福建物构所，副研究员

2005.01-2014.10 中科院福建物构所，研究员

2014.10-至今 北京师范大学， 教授

研究方向

非线性光学晶体材料，热电材料。

科研项目

1. 新颖单氟磷酸盐化合物的合成，结构及深紫外非线性光学性能研究；国家基金面上项目；2020-2023；主持

2. 新型无机倍频晶体材料的化学创制；国家自然科学基金重大项目；2022-2026；参与

3. 基于全尺度空间重构的近室温高性能热电材料宏量制备与高功率器件应用集成；科技部国家重点研发项目；2023-2025；参与

出版著作

1．《材料X射线衍射基础与实践》，化学工业出版社2023年版

2．《固体无机化学基础及新材料的设计合成》，高等教育出版社2012年版

发表论文

1、Yin, J. P.; Guo, J. Y.; Huo, H.; Liu, X.; Cheng, X. J.; Lin, Z. S.; Wu, L.-M.;* Chen, L.* Enhanced Coplanarity and Giant Birefringence in Hydroxypyridinium Nitrate via Hydrogen Bonding between Planar Donors and Planar Acceptors. Angew. Chem. Int. Ed. 2024, DOI: 10.1002/anie.202417579.

2、 Liu, Q. Q.; Liu, X.; Li, M. Z.; Wang, R. X.; Li, B. X.; Wu, L.-M.;* Chen, L.* LiLnGeS₄ (Ln = La–Nd): Designing High Performance Infrared Nonlinear Optical Sulfides through “Band Reformation of AGS”. Angew.Chem. Int. Ed. 2024, e202415318

3、Zhang, Z. P.; Liu, X.; Wang, R. X.; Zhao, S.; He, W. J.; Chen, H. Y.; Deng, X. B.; Wu, L.-M.;* Zhou, Z. Y.;* Chen, L.* Remarkable Second Harmonic Generation Response in (C₅H₆NO)⁺(CH₃SO₃)⁻: Unraveling the Role of Hydrogen Bond in Thermal Driven Nonlinear Optical Switch. Angew. Chem. Int. Ed. 2024, 63 , e202408551.

4、Liu, X.; Yang, Y. C.; Li, M. Y.; Chen, L.;* Wu, L.-M.* Anisotropic Structure Building Unit Involving Diverse Chemical Bonds: a New Opportunity for High-Performance Second-Order NLO Materials. Chem. Soc. Rev. 2023, 52, 8699–8720.

5、Jia, F.; Zhao, S.; Wu, J.; Chen, L.;* Liu, T.-H.;* Wu, L.-M.* Cu₃BiS₃: Two-Dimensional Coordination Induces Out-of-Plane Phonon Scattering Enabling Ultralow Thermal Conductivity. Angew. Chem. Int. Ed. 2023, 62, e202315642.

6、Li, F.; Liu, X.; Ma, N.; Yang, Y. C.; Yin, J. P.; Chen, L.;* Wu, L.-M.* Overdamped Phonon Diffusion and Nontrivial Electronic Structure Leading to a High Thermoelectric Figure of Merit in KCu₅Se₃. J. Am. Chem. Soc. 2023, 145, 14981−14993.

7、Yang, Y. C.; Liu, X.; Zhu, C. F.; Zhu, L.; Wu, L.-M.;* Chen, L.* Inorganic Solid-State Nonlinear Optical Switch with a Linearly Tunable T c Spanning a Wide Temperature Range. Angew. Chem. Int. Ed. 2023, 62, e202301404.Jia, F.; Yin, X.; Cheng, W. W.; Lan, J. T.; Zhan, S. H.; Chen, L.;* Wu, L.-M.*

8、Room-Temperature High-Performance Thermoelectric Bi_0.6Sb_0.4Te: Elimination of Detrimental Band Inversion in BiTe. Angew. Chem. Int. Ed. 2023, 62, e202218019.

9、Xu, D.; Liu, X.; Wang, J.; Liu, Q. Q.; Fu, R.; Lin, H.; Chen, L.;* Wang, L. M.;* Wu, L.-M.* Atomic Structural Origin of Fictive Temperature Revealed by AZnP₃O₉ (A = K, Rb) Glasses. Angew. Chem. Int. Ed. 2023, 62, e202218666.

10、Li, R. A.; Liu, Q. Q.; Liu, X.; Liu, Y.; Jiang, X.; Lin, Z.; Jia, F.; Xiong, L.; Chen, L.;* Wu, L.-M.* Na₂Ba[Na₂Sn₂S₇]: Structural Tolerance Factor-guided NLO Performance Improvement. Angew. Chem. Int. Ed. 2023, 62, e202218048.

11、Li, F.; Liu, X.; Ma, N.; Chen, L.;* Wu, L.-M.* Thermoelectric Zintl Compound In_1-xGa_xTe: Pure Acoustic Phonon Scattering and Dopant-Induced Deformation Potential Reduction and Lattice Shrink. Angew. Chem. Int. Ed. 2022, 61, e202208216.

12、Liu, J. Y.; Chen, L.;* Wu, L.-M.* Ag₉GaSe₆: High-Pressure-Induced Ag Migration Causes Thermoelectric Performance Irreproducibility and Elimination of Such Instability. Nat. Commun. 2022, 13, 2966, https://doi.org/10.1038/s41467-022-30716-7.

13、Liu, Q. Q.; Liu X.; Wu, L.-M.;* Chen, L.* SrZnGeS₄: A Dual-Waveband Nonlinear Optical Material with A Transparency Spanning UV–Vis and Far-IR Spectral Regions. Angew. Chem. Int. Ed. 2022, 61, e202205587.

14、Zhang, Z. P.; Liu, X.; Liu, X. M.; Lu, Z. W.; Sui, X.; Zhen, B. Y.; Lin, Z. S.; Chen, L.;* Wu, L. M.* Driving Nonlinear Optical Activity with Dipolar 2‑Aminopyrimidinium Cations in (C₄H₆N₃)⁺(H₂PO₃)⁻. Chem. Mater. 2022, 34, 1976−1984.

15、Liu, X.; Chen, L.;* Wu, L. M* Why does KBe₂BO₃F₂ have Excellent Deep Ultraviolet Nonlinear Optical Properties? Sci. China. Chem. 2022, 48, 1–9.

16.Ma, N.; Li, F.; Li, J. G.; Liu, X.; Zhang, D. B.; Li, Y. Y.; Chen, L.;* Wu, L. M.* Mixed-Valence CsCu₄Se₃: Large Phonon Anharmonicity Driven by the Hierarchy of the Rigid [(Cu⁺)₄(Se²⁻)₂](Se⁻) Double Anti-CaF₂ Layer and the Soft Cs⁺ Sublattice. J. Am. Chem. Soc. 2021, 143 , 18490−18501.

17.Xiong, L.; Wu, L. M.;* Chen, L.* A General Principle for DUV NLO Materials: π -Conjugated Confinement Enlarges Band Gap. Angew. Chem. Int. Ed. 2021, 60, 25063–25067.

18.Yang, Y. C.; Liu, X.; Lu, J.; Wu, L. M.;* Chen, L.* [Ag(NH₃)₂]₂SO₄: A Strategy for the Coordination of Cationic Moieties to Design Nonlinear Optical Materials. Angew. Chem. Int. Ed. 2021, 60, 21216–21220.

19.Lu, J.; Liu, X.; Zhao, M.; Deng, X. B.; Shi, K. X.; Wu, Q. R.; Chen, L.;* Wu, L. M.* Discovery of NLO Semiorganic (C₅H₆ON)⁺(H₂PO₄)⁻: Dipole Moment Modulation and Superior Synergy in Solar-Blind UV Region. J. Am. Chem. Soc. 2021, 143, 3647-3654.

20.Jia, F.; Liu, Y. Y.; Zhang, Y. F.; Shu, X.; Chen, L.;* Wu, L. M.* Bi8Se7: Delocalized Interlayer π Bond Interactions Enhancing Carrier Mobility and Thermoelectric Performance Near Room Temperature. J. Am. Chem. Soc. 2020, 142, 12536−12543.

21.Li, R. A.; Zhou, Z. Y.; Lian, Y. K.; Jia, F.; Jiang, X. X.; Tang, M. C.; Wu, L. M.;* Sun, J. L.;* Chen, L.* A2SnS5: Structural Incommensurate Modulation Exhibiting Strong Second-Harmonic Generation and High Laser Induced Damage Threshold (A = Ba, Sr). Angew. Chem. Int. Ed. 2020, 59 , 11861−11865.

22.Pan, C. Y.; Yang, X. R.; Xiong, L.; Lu, Z. W.; Zhen, B. Y.; Sui, X.; Deng, X. B.; Wu, L. M.;* Chen, L.* Solid-State Nonlinear Optical Switch with the Widest Switching Temperature Range Owing to Its Continuously Tunable Tc. J. Am. Chem. Soc. 2020, 142 , 6423−6431.

23.Ma, N.; Li, Y. Y.; Chen, L.;* Wu, L. M.* α‑CsCu5Se3: Discovery of a Low-Cost Bulk Selenide with High Thermoelectric Performance. J. Am. Chem. Soc. 2020, 142 , 5293−5303.

24.Ma, N.; Xiong, L.; Chen, L.;* Wu, L. M.* Vibration Uncoupling of Germanium with Different Valence States Lowers Thermal Conductivity of Cs2Ge3Ga6Se14. Sci. China Mater. 2019, 62 (12): 1788–1797.

25.Lu, J.; Lian, Y. K.; Xiong, L.; Wu, Q. R.; Zhao, M.; Shi, K. X.; Chen, L.;* Wu, L. M.* How To Maximize Birefringence and Nonlinearity of π‑Conjugated Cyanurates. J. Am. Chem. Soc. 2019, 141 , 16151−16159.

26.Zhou, H. M.; Xiong, L.; Chen, L.;* Wu, L. M.* Dislocations that Decrease Size Mismatch within the Lattice Leading to Ultrawide Band Gap, Large Second-Order Susceptibility, and High Nonlinear Optical Performance of AgGaS2. Angew. Chem. Int. Ed. 2019, 58 , 9979−9983.

27.Lu, J.; Yue, J. N.; Xiong, L.; Zhang, W. K.; Chen, L.;* Wu, L. M.* Uniform Alignment of Non-π-Conjugated Species Enhances Deep Ultraviolet Optical Nonlinearity. J. Am. Chem. Soc. 2019, 141 , 8093−8097.

28.Xiong, L.; Chen, J.; Lu, J.; Pan, C. Y.; Wu, L. M.* Monofluorophosphate: A New Source of Deep-Ultraviolent Nonlinear Optical Materials. Chem. Mater. 2018, 30 , 7823−7830.

29.Chen, J.; Xiong, L.; Chen, L.;* Wu, L. M.* Ba2NaClP2O7: Unprecedented Phase Matchability Induced by Symmetry Breaking and Its Unique Fresnoite-type Structure. J. Am. Chem. Soc. 2018, 140, 14082−14086.

30.Ju, S. L.; + Bai, W.; + Wu, L. M.; + Lin, H.; Xiao, C.*; Cui, T. S.; Li, Z.; Kong, S.; Liu, Y.; Liu, D. Y.; Zhang, G. B.; Sun, Z.*; Xie, Y.* Evidence for Itinerant Carriers in an Anisotropic Narrow-Gap Semiconductor by Angle-Resolved Photoemission Spectroscopy. Adv. Mater. 2018, 30 , 1704733.

31.Yin, X.; Liu, J. Y.; Chen, L.; Wu, L. M.* High Thermoelectric Performance of In4Se3-Based Materials and the Influencing Factors. Acc. Chem. Res. 2018, 51 , 240−247.

32.Li, Y. Y.; Liu, P. F.; Wu, L. M.* Ba6Zn7Ga2S16: A Wide Band Gap Sulfide with Phase-Matchable Infrared NLO Properties. Chem. Mater . 2017, 29 , 5259−5266.

33.Lin, H.; Chen, L.;* Yu, J. S.; Chen, H.; Wu, L. M.* Infrared SHG Materials CsM3Se6 (M = Ga/Sn, In/Sn): Phase Matchability Controlled by Dipole Moment of the Asymmetric Building Unit. Chem. Mater. 2017, 29 , 499–503.

34.Lin, H.; Chen, H.; Zheng, Y. J.; Chen, Y. K.; Yu, J. S.; Wu, L. M.* Ba5Cu8In2S12: A Quaternary Semiconductor with a Unique 3D Copper-rich Framework and Ultralow Thermal Conductivity. Chem. Commun . 2017, 53 , 2590−2593.

35.Lin, H.+; Tan, G. J.+; Shen, J. N.; Hao, S. Q.; Wu, L. M.;* Calta, N.; Malliakas, C.; Wang, S.; Uher, C.; Wolverton, C.; Kanatzidis, M. G.* Concerted Rattling in CsAg5Te3 Leading to Ultralow Thermal Conductivity and High Thermoelectric Performance. Angew. Chem. Int. Ed. 2016, 55 , 11431–11436.

36.Shi, Y. F.; Chen, Y. K.; Chen, M. C.; Wu, L. M.;* Lin, H.; Zhou, L. J.; Chen, L.* Strongest Second Harmonic Generation in the Polar R3MTQ7 Family: Atomic Distribution Induced Nonlinear Optical Cooperation. Chem. Mater. 2015, 27 , 1876−1884.

37.Yu, P.; Wu, L. M.;* Zhou, L. J.; Chen, L.* Deep-ultraviolet Nonlinear Optical Crystals: Ba3P3O10X (X = Cl, Br). J. Am. Chem. Soc. 2014, 136 , 480-487.

38.Shen, J. N.; Wu, L. M.;* Zhang, Y. F. First-principles Studies of the TE Properties of [110]-Ge/Si Core/shell Nanowires with Different Surface Structures. J. Mater. Chem. A 2014, 2, 2538-2543.

39.Zhou, L. J.; Zhang, Y. F.; Wu, L. M.* SiC2 Siligraphene and Nanotubes: Novel Donor Materials in Excitonic Solar Cells. Nano Lett. 2013, 13 , 5431-5436.

40.Lin, H.; Chen, L.;* Zhou, L. J.; Wu, L. M.* Functionalization Based on the Substitutional Flexibility: Strong Middle IR Nonlinear Optical Selenides AXII4XIII5Se12. J. Am. Chem. Soc. 2013, 135 , 12914–12921.

41.Lin, Z. S.; Chen, L.; Wang, L. M.; Zhao, J. T.; Wu, L. M.* A Promising Mid-temperature Thermoelectric Material Candidate: Pb/Sn-codoped In4PbxSnySe3. Adv. Mater. 2013, 25 , 4800–4806.

42.Li, L. H.; Chen, L.;* Li, J. Q.; Wu, L. M.* Structural Characteistics, Electronic Structure, and Thermoelectric Property of New Sb-based Type-I clathrates From Density Functional Theory Calculations. Chem. Mater. 2010, 22 , 4007–4018.

43.Wu, L. M.; Wu, X. T.; Chen, L.* Structural Overview and Structure-property Relationships of Iodoplumbate and Iodobismuthate. Coord. Chem. Rev. 2009, 253 , 2787–2804.

44.Wu, L. M. ; Kim, S. H.; Seo, D. K.* Electron-precise/deficient La5-xCaxGe4 (3.4 ≤ x ≤ 3.8) and Ce5-xCaxGe4(3.0 ≤ x ≤ 3.3):  Probing Low-valence Electron Concentrations in Metal-rich Gd5Si4-type Germanides. J. Am. Chem. Soc. 2005, 127 , 15682-15683.

45.Wu, L. M.; Seo, D. K.* Mn14Al56+xGe3-x(x = 0-0.6): A New Intermetallic Phase Containing Unprecedented "Half-broken" Mackay Icosahedra as Building Units. J. Am. Chem. Soc. 2004, 126 , 4398−4403.

46.Chen, L.; Chen, Y. B.; Wu, L. M.* Synthesis of Uniform Cu2S Nanowires from Copper-thiolate Polymer Precursors by a Solventless Thermolytic Method. J. Am. Chem. Soc. 2004, 126 , 16334−16335.

47.Wu, L. M.; Seo, D. K.* New Solid-gas Metathetical Synthesis of Binary Metal Polysulfides and Sulfides at Intermediate Temperatures: Utilization of Boron Sulfides. J. Am. Chem. Soc. 2004, 126 , 4676−4681

教学工作

本科生： 化学综合设计实验

研究生： 现代化学进展；合成实验

社会工作

2014-2018年 中国材料研究学会热电材料及应用分会 理事

2018-2022年 中国材料研究学会热电材料及应用分会 理事

2020年起应邀担任Journal of Solid State Chemistry 杂志国际编委